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In February 2003, Mirza was given a wildcard to play in her first ever WTA tournament, at the Hyderabad Open, in her hometown. She lost the tough first round encounter to Australia's Evie Dominikovic in three sets. The following week, at the Qatar Ladies Open, she fell to Czech Olga Blahotová in the first qualifying round. She had a good result representing India on the Fed Cup, winning three straight matches. She helped India win a bronze medal in the mixed doubles event of the 2002 Asian Games in Busan, partnering Leander Paes. In addition, Mirza picked up four gold medals at the 2003 Afro-Asian Games in Hyderabad.

She reached the quarterfinals in San Diego, the semifinals at Cincinnati, and made it to the final at Stanford. She also won the doubles event in Cincinnati with Shahar Pe'er. At the US Open, she reached the third round before losing to Anna Chakvetadze for the third time in recent weeks. She fared much better in the doubles competition, reaching the quarterfinals in mixed doubles with her partner Mahesh Bhupathi and the quarterfinals in the women's doubles with Bethanie Mattek, including a win over number two seeds Lisa Raymond and Samantha Stosur. She won four doubles titles in 2007.

Mirza reached the quarterfinals at Hobart as the No. 6 seed and lost to Flavia Pennetta in three sets. She reached the third round at the Australian Open as No. 31 seed, in which she lost to No. 8 seed Venus Williams having been up a break in the first set. She ended runner-up in the Australian Open mixed doubles partnering Mahesh Bhupathi, where they lost in straight sets to Sun Tiantian and Nenad Zimonjić.

Mirza started her year by playing at the doubles event of the Hobart International. Partnering Francesca Schiavone, they reached the quarterfinals. At 2009 Australian Open, she won her first-round match against Marta Domachowska, but she fell against tenth seed Nadia Petrova in round two. In doubles she lost in the first round partnering Vania King. But in mixed doubles, Mirza picked up her first Australian Open Grand Slam title. Partnering with Mahesh Bhupathi, she beat Nathalie Dechy and Andy Ram in the final.

She then entered the Pattaya Women's Open and reached the final after a string of good performances but lost to Vera Zvonareva. She made the semifinals in doubles in the same tournament. Mirza then competed in Indian Wells where she lost in the second round to Flavia Pennetta. She then lost to Mathilde Johansson in the first round of the Miami Open. However, Mirza and her doubles partner Chuang Chia-jung made the semifinals of the women's doubles. Mirza also lost in the first round of the MPS Group Championships but won the doubles title with Chuang. She again lost in the first round at Roland Garros, to Galina Voskoboeva. On grass, Mirza participated at the Birmingham Classic and reached the semifinals, losing to Magdaléna Rybáriková. At Wimbledon, Mirza defeated Anna-Lena Grönefeld in the first round, before falling to No. 28 seed Sorana Cîrstea in the second. She also lost in the second round of the doubles (with Chuang) and mixed doubles (with Bhupathi).

In November, she represented India at the 2010 Asian Games. The unseeded Indian defeated Chan Wing-yau in the first round. Next, she defeated sixth seed Zhang Shuai in straight sets to enter into quarterfinal. In the quarterfinal, Mirza won against second seed Tamarine Tanasugarn to move in semifinal, where she was defeated by third seed Akgul Amanmuradova and won bronze medal in singles. In mixed doubles, she partnered with India's Vishnu Vardhan losing in the finals to Chan Yung-jan and Yang Tsung-hua and won silver medal. In December, she went to Dubai to compete at the Al Habtoor Challenge. Coming unseeded, she won the tournament, defeating Ksenia Pervak, top seed Julia Görges and Evgeniya Rodina en route, and second seed Bojana Jovanovski in the final.

Going into the Australian Open, Mirza was overpowered by Tsvetana Pironkova in the first round. In doubles, she reached her third Grand Slam semifinal, partnering Vesnina, where they fell to Svetlana Kuznetsova and Vera Zvonareva. For the mixed-doubles event, Mirza played alongside compatriot Mahesh Bhupathi and reached her fourth Grand Slam semifinal.

She then participated in the French Open in the women's doubles (with Mattek-Sands) and the French Open mixed doubles (with Bhupathi). In the doubles she suffered a first-round shock defeat but found great success in the French Open mixed-doubles where she and Bhupathi won the crown by defeating Santiago González of Mexico and Klaudia Jans-Ignacik of Poland in the final on 7 June 2012.[27]

Mirza, partnering Rushmi Chakravarthy in the women's doubles competition at Olympics, bowed out, losing to Chinese Taipei team in a tight match.[32] She also lost in quarterfinals of mixed doubles with Leander Paes to Belarus in a tough encounter. At the Premier Mandatory events of Montréal and Cincinnati, partnering Mattek-Sands, Mirza reached the quarterfinals and lost in round one of doubles, respectively.[33]

Mirza kicked off her 2013 season with a title Brisbane alongside Bethanie Mattek-Sands in the first tournament itself. The pair then unexpectedly lost in the first round of Australian Open, Mirza though reached the quarterfinals of the 2013 Australian Open mixed doubles partnering Bob Bryan. Mattek-Sands and Mirza then won the doubles title at the Dubai Tennis Championships in February. They had to retire in their round of 16 match at the French Open after having won the first set against Anastasia Pavlyuchenkova and Lucie Šafářová. They also lost in the round of 16 at Wimbledon. Mirza then formed a brief successful partnership with Zheng Jie from China winning a title at New Haven and reaching the semis at US Open losing out to Australians Casey Dellacqua and Ashleigh Barty. Mirza then partnered Cara Black for the rest of the season and the pair won their first title in their first outing at Tokyo. They won their second title in a row as they lifted the China Open trophy defeating top seeds and world-number-ones, Sara Errani and Roberta Vinci, en route. Mirza partnered different players during 2013 and won five WTA titles.

Mirza and Black recorded three consecutive quarterfinal finishes in the subsequent clay tournaments, namely the Madrid Open, the Italian Open, and the French Open. In the mixed doubles event at the 2014 French Open, Mirza and Horia Tecău lost in the second round to Tímea Babos and Eric Butorac. Mirza began grass-court season playing in Birmingham. She and Black lost to Raquel Kops-Jones and Abigail Spears in the semifinals. At the Eastbourne International, they reached the quarterfinals before losing to Chan Hao-ching and Chan Yung-jan. The pair next competed at the Wimbledon Championships and lost in the second round to the unseeded pairing of Anastasia Pavlyuchenkova and Lucie Šafářová.[35]

Mirza and Black next competed in the 2014 US Open and lost to the pairing of Martina Hingis and Flavia Pennetta in the semifinals. Mirza played the mixed doubles in the US Open pairing with Bruno Soares and went on to become the 2014 US Open mixed-doubles champions, thereby winning the third mixed doubles Grand Slam in her career.

Sania won a gold and bronze at the 17th Asian Games in Incheon, South Korea. She paired with Saketh Myneni to beat China's Hsien Yin Peng and Chan Hao-ching and win gold in the mixed doubles tournament. She also won a bronze medal in women's doubles tournament, where she paired with Prarthana Thombare.

Mirza participated in the International Premier Tennis League starting on 28 November 2014, playing with the Micromax Indian Aces alongside tennis legend Roger Federer, countryman Rohan Bopanna, Ana Ivanovic and Gaël Monfils. She played all the mixed-doubles matches alongside Bopanna and partnered Federer who visited the country for his first match there in the New Delhi leg, much to her personal and fans' delight.[36] Mirza won the majority of her matches and played a key role for the Indian Aces to win the inaugural edition of the IPTL 2014.[37]

Mirza and Hingis won Family Circle Cup's double title in April 2015 defeating Casey Dellacqua and Darija Jurak and with the title win Mirza became the first Indian to be ranked world No. 1 in WTA's doubles rankings.[4] It was Mirza and Hingis' third successive title win and they have not lost as a single match since joining forces, winning 14 matches in a row. "It's a dream for every kid to be No. 1 one day." Mirza said after her win. And on reaching No. 1 in Charleston she added "No tournament has been as special to me as the Family Circle Cup and no tournament will ever be as special to me, because I became No. 1 here."[46] They were routed in the first round at the Porsche Tennis Grand Prix. They reached the finals of Italian Open but lost to the team of Tímea Babos and Kristina Mladenovic. They lost in the quarterfinals of French Open to Mattek-Sands and Šafářová where the duo were the top seeds. Mirza was also given the top seeding with her partner Bruno Soares in the mixed doubles event. In spite of this, the pair lost in just 56 minutes against the unseeded Anna-Lena Grönefeld and Jean-Julien Rojer in the first round.[47]

After both Mahesh Bhupathi and Rohan Bopanna refused to play in the men's doubles event at the 2012 Olympics with Leander Paes, Paes demanded that he be partnered with Mirza for the mixed doubles event. Mirza accused the All India Tennis Association (AITA) of using her as 'bait' to keep Paes happy as she wanted to play with Bhupathi, with whom she has won 2 grand slams. In the end, Mirza was paired with Paes and the pair lost in the quarterfinals of the mixed doubles.[99]

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